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The same atom, two arrangements

Why Is Diamond Hard and Pencil Lead Soft?

Diamond and pencil lead are both pure carbon — one is bonded in every direction, the other in slippery flat sheets.

Diamond Every atom bonded allways — hardest there isPencil lead Flat sheets that slide— softest there is
Both are nothing but carbon atoms.
  1. Step 1 of 5

    Both are pure carbon. Nothing else.

    A diamond Carbon — and only carbon

    There is no ingredient in a diamond that is missing from a pencil. Burn either one in enough oxygen and you get the same gas out.

  2. Step 2 of 5

    In diamond, every atom is tied to four neighbours.

    Each atom bonded tofour othersBonds point every wayat onceThe whole stone is onenetNothing slides — it canonly break

    The bonds point out in all directions, so the whole stone is a single net. To scratch it you have to break bonds, not just slide something.

  3. Step 3 of 5

    In pencil lead, the atoms lie in flat sheets.

    A sheet of carbonvery stronglybonded insideBarely anything holdingthemthe sheets slipapartAnother sheetwhich is whatends up on yourpaper

    Inside each sheet the bonds are extremely strong. Between the sheets they are feeble, so the sheets slide off each other at the lightest touch.

  4. Step 4 of 5

    Writing is sheets being left behind.

    1 Drag it overpaper2 Sheets shearoff3 They snag onthe paperfibres

    Drag a pencil across paper and you are shearing off layers of carbon and leaving them on the fibres. The grey line is a stack of slid-off sheets.

  5. Step 5 of 5

    Hardness is really about which bonds have to break.

    Diamondhardest naturalsubstanceQuartz — beach sandscratches glassGraphiteyou can rub itoff with afinger

    Diamond scratches everything because every direction is a strong bond. Graphite marks everything because one direction has almost no bond at all.

    Turning graphite into diamond takes about 1,500°C and 50,000 times the pressure of the air around you. Deep underground both happen at once, which is where natural diamonds come from.

The short version

Diamond and pencil lead are the same carbon atoms — hard when every bond points a different way, soft when the bonds lie in sheets that slide.

Try it yourself

Rub a pencil mark with your fingertip. The smudge is carbon sheets sliding — the exact reason a pencil writes at all.

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