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ELI5 Yahaaa

Tangled springs

Why Does Rubber Bounce Back?

Stretch a rubber band and you are not pulling molecules apart. You are straightening out tangled ones.

Relaxed Long molecules in aloose tangleStretched The same moleculespulled straight
Nothing breaks. Something uncoils, and wants to coil back.
  1. Step 1 of 5

    It starts as tree sap.

    1 A cut is madein the bark2 White sap runsinto a cup3 It is driedinto solidrubber

    Cut the bark of a rubber tree and a white liquid runs out. It is the tree's own defence against damage, collected in a cup, and it is where natural rubber begins.

  2. Step 2 of 5

    The molecules are tangled springs.

    A loose random tangle Pullingstraightensthem Straight, and under strain Let go — theytangle again

    Rubber is made of extremely long molecules lying in a random tangle. Pull, and they straighten out. Let go, and they scramble back into a tangle, because tangled is simply far more likely.

  3. Step 3 of 5

    Raw rubber is nearly useless.

    Warm day Raw rubber goes softand stickyCold day It goes hard and cracks

    On its own it goes sticky in summer and hard and brittle in winter. Early rubber goods melted on shop shelves, and the whole trade very nearly collapsed.

  4. Step 4 of 5

    Cooking it with sulphur fixed that.

    An ordinary rubberband Bridges tying the chainstogether

    Heat rubber with sulphur and small bridges form between the long molecules. Now they can still uncoil, but they cannot slide past each other — so it stays springy hot or cold.

  5. Step 5 of 5

    Stretching it warms it up.

    Stretched quickly It genuinely warmsup

    Put a rubber band to your lip and stretch it quickly — it feels warmer. Let it snap back and it cools. Almost no other material does anything so obvious with a simple pull.

    Most rubber today is made from oil rather than trees, but tyres for heavy vehicles still use natural rubber, because nothing artificial handles the heat as well.

The short version

Rubber bounces back because pulling straightens its long tangled molecules, and they scramble back the moment you let go.

Try it yourself

Stretch a wide rubber band against your lip, hold it, then let it snap back. Warm, then cool. You can feel both.

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