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Locking into a pattern

What Happens When Water Freezes?

Freezing locks water molecules into an open lattice — which is why ice expands.

Water Molecules sliding,packed closeIce Locked in an openlattice — more space
Water is one of the few things that expands on freezing.
  1. Step 1 of 5

    Cooling slows molecules down.

    Warm watermolecules movefastCold watermuch slowerIcevibrating inplace

    Temperature is molecular motion. Removing heat means removing movement, until attraction between molecules can finally win.

  2. Step 2 of 5

    At 0°C they lock into place.

    1 Liquid —sliding freely2 Reaches 0°C3 Locked intoposition

    Molecules stop sliding and settle into fixed positions. That transition is freezing, and it happens at one specific temperature.

  3. Step 3 of 5

    The pattern is deliberately open.

    Ice A hexagonal lattice withgaps built in

    Water molecules link at 120-degree angles, which forces a hexagonal lattice with gaps in it. The gaps are why ice takes more room.

  4. Step 4 of 5

    So ice takes up more space than water.

    Water CompactIce About 9% larger

    About 9 percent more. That is why bottles crack in the freezer and why frozen pipes burst — the expansion is unstoppable.

  5. Step 5 of 5

    Which is why ice floats.

    Ice floats on topinsulatinglayerLiquid water belowfish survivethe winter

    The same mass in more space means lower density. Ponds freeze from the top down, leaving fish alive in liquid water below.

    If ice sank, ponds and lakes would freeze solid from the bottom and most freshwater life would not survive.

The short version

Freezing locks water into an open hexagonal lattice, so ice expands and floats — which keeps lakes liveable.

Try it yourself

Fill a plastic bottle to the brim, cap it and freeze it. It bulges — the expansion is genuinely unstoppable.

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